Nasty! Unfortunately it is a double whammy if you unscrew the cap on a pressurised cooling system before it has cooled. Even though it might not have been boiling before, if you suddenly depressurise a vehicle cooling system, it is possible that the water inside will be hot enough to come to a boil instantly once the pressure is reduced to normal atmospheric pressure. So, when you do this the water very suddenly and explosively starts to boil, i.e. turn into its gaseous form which is steam, and this gas expands the volume of the coolant and forces water and steam out of the small opening at